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Gas laws

States of Matter

There are three states of matter, whose structure and behaviour are explained by the kinetic theory: the atoms in any substance have energy proportional to the temperature. This energy causes motion, and the degree of movement the atoms or molecules have depends on the strength of the attractive forces, or bonds, between them.

Since all substances have different bonding strengths, the amount of energy needed to break these bonds is different. This is why, for example, it is necessary to heat iron to 1538 °C to melt it, while ice melts at 0 °C.


Particles in a solid
Particles in a solid are strongly bonded and vibrate in a fixed place

Solids are strongly bonded. This means the atoms attract each other so strongly they cannot move around, and vibrate within a rigid structure, with the atoms are fixed in the one place.

The kinetic theory says that atoms vibrate back and forth within a structure. How much energy is needed to break these bonds determines the melting point of the substance. Every substance has its own unique melting point, which depends on the elements which compose the solid.

Particles in a liquid
Particles in a liquid are loosely bonded and free to move


Liquids are weakly bonded. This means they still attract each other, but less than in a solid. They have too much kinetic energy for the attractive forces to hold them in the one place, so are able to move around and past each other without being held together. Since the molecules are free to move around, they take the shape of a container they are in.


Particles in a gas
Particles in a gas are not bonded and have high kinetic energy

Gas has so much kinetic energy that the molecules are not bonded together at all. This high kinetic energy causes them to push against anything they hit, such as the walls of their container. This creates a pressure which is proportional to their thermal energy (temperature).

The gas pressure depends on the amount of gas (number of molecules), not what type of molecule they are.

The pressure will increase if the temperature increases. Conversely, if the volume the gas occupies increases, the pressure and the temperature will decrease. That is why it is colder on top of a mountain than at sea level, and the air is 'thinner' (lower pressure).

Water: 3 states at once

Iceberg on water with clouds behind: three states of matter for the one substance

The kinetic theory states that all atoms and molecules which compose a substance have some thermal energy, causing them to vibrate in situ or move.

Ice has a temperature below 0°C, and forms a rigid structure of the $H_2O$ molecules. As you can see, ice has a lower density than liquid water, so floats. It has come in from a colder location and is melting.

The water around it has a temperature above 0°C. In time the water and the ice will reach the same temperature. Either the water freezes and forms more ice, or the ice melts and joins the water.

The clouds are not gas. They are composed of tiny droplets of of water. However, there is invisible water gas in the air. All liquids exchange molecules with the air as they try to balance out the temperature difference.

Content © Andrew Bone. All rights reserved. Created : May 25, 2014 Last updated :June 23, 2015

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